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Figure \(\pageindex{2}\): crystal field theory splitting diagram. Example of influence of ligand electronic properties on d orbital splitting. This shows the comparison of low-spin versus high-spin electrons. Paramagnetic high-spin complexes and correspond to those in which, despite the d orbitals being split, there are still four unpaired electrons diamagnetic low-spin and correspond to those in which electrons are doubly occupying three orbitals, leaving two unoccupied. High- 4and low-spin complexes exist for octahedral d, d5, d6. Spin free complex means that the electrons are free to spin! high spin complexes are the ones with weak field ligands which aren’t able to pair up electrons of the central ion. Hence the 2 terms are usually used synonymously. On the same lines low spin complexes and spin paired complexes are used synonymously! Spin free complex means that the electrons are free to spin! high spin complexes are the ones with weak field ligands which aren't able to pair up electrons of the central ion. Hence the 2 terms are usually used synonymously. On the same lines low spin complexes and spin paired complexes are used synonymously! Step 1 of 3. In the complex the cation is so, cobalt is in (+iii) oxidation state. The electronic configuration of is. All the electrons become paired in the low spin complex. So no unpaired electrons present i. (zero) the electron distribution in the complex is shown below. When a complex has only one d electron, the analysis is simple. For example, ti in [ti (oh 2) 6] 3+ is a d 1 ion, and an electron occupies the t 2g orbital produced by the octahedral ligand field splitting. 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